To name an alkane from a Newman projection you convert the projection to a line structure; then you write the IUPAC name.
EXAMPLE:
Name the alkane shown in the following Newman projection.
Solution:
One C atom is at the front of the circle. Another C atom hides behind the circle. You must trace the bonds through the structure.
Pick the longest chain from one of the three groups attached to the front C atom.
Since they are all CH groups pick one of them. Label that CH carbon C-1.
C-1 attaches to C-2 the front carbon.
C-2 attaches to the other two CH groups and to the hidden C-3. Label the front carbon C-2.
C-3 attaches to two H atoms and a CHCH group. Pick the longest group (CHCH) to form the rest of the chain.
Label the CH carbon as C-4.
Label the CH carbon as C-5.
You now have the longest chain in the molecule.
Draw the line structure.
C-1 = CH
C-2 = C(CH)
C-3 = CH
C-4 = CH
C-5 = CH
Your structure should look something like the structure below.
Write the IUPAC name.
The alkane is 22-dimethylpentane.